/playlist/trackList/track/title

XmlDocument xml = new XmlDocument();
xml.Load("music.xml");
XmlNamespaceManager xnm = new XmlNamespaceManager(xml.NameTable);
xnm.AddNamespace("x", "http://xspf.org/ns/0/");
string xpath = "/x:playlist/x:trackList/x:track/x:title";
foreach (XmlNode xn in xml.SelectNodes(xpath, xnm))
{
Console.WriteLine(xn.InnerText);
}

$xml = simplexml_load_file('music.xml');
$xml->registerXPathNamespace('x','http://xspf.org/ns/0/');
$xpath = '/x:playlist/x:trackList/x:track';
$result = $xml->xpath($xpath);
foreach($result as $row){
echo $row->title;
}